BARF-catalyzed C-H bond alkenylation and alkylation of ferrocenes

Satoshi Takebayashi, Takanori Shibata

研究成果: Article査読

64 被引用数 (Scopus)

抄録

[Ir(cod) 2]BARF [BARF = tetrakis(3,5-trifluoromethylphenyl) borate] catalyzed the directed alkenylation and alkylation of ferrocenes to form a variety of tri- and disubstituted ferrocenes. Mechanistic investigation revealed several putative intermediates along with the importance of COD (1,5-cyclooctadiene), as a diene ligand, and a possible catalyst deactivation pathway. On the basis of the mechanistic investigation, catalytic activity was further improved.

本文言語English
ページ(範囲)4114-4117
ページ数4
ジャーナルOrganometallics
31
11
DOI
出版ステータスPublished - 2012 6 11

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 有機化学
  • 無機化学

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