BINAM- mono -PHOS as new entry for multinuclear copper catalysts in asymmetric conjugate addition of organozinc reagents

Kohei Endo*, Ryotaro Takayama, Takanori Shibata

*この研究の対応する著者

研究成果: Article査読

12 被引用数 (Scopus)

抄録

The readily functionalized ligands, BINAM-PHOS, participate in the copper-catalyzed asymmetric conjugate addition of organozinc reagents to enones. The incorporation of benzoyl derivatives on nitrogen atoms was crucial to promote the reaction. Notably, BINAM-PHOS derivatives gave the opposite major enantiomers to that obtained using BINOL-PHOS derivatives, which we have developed for the construction of multinuclear catalysts.

本文言語English
論文番号ST-2013-U0225-L
ページ(範囲)1155-1159
ページ数5
ジャーナルSynlett
24
9
DOI
出版ステータスPublished - 2013 4月 25

ASJC Scopus subject areas

  • 有機化学

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