Bridging fullerenes with metals

Dam Hieu Chi, Y. Iwasa, X. H. Chen, T. Takenobu, T. Ito, T. Mitani, E. Nishibori, M. Takata, M. Sakata, Y. Kubozono

研究成果: Article査読

8 被引用数 (Scopus)

抄録

The bonding nature between rare earth metals and fullerene molecules has been investigated. The electron density distribution for nominal Sm3C70, calculated by a maximum entropy method (MEM) based on the Rietveld analysis of synchrotron X-ray diffraction pattern, unambiguously demonstrated a covalent Sm-C bond, which is almost as strong as the interatomic bonding of crystal Si. Furthermore, the Sm bridges two C70 molecules, producing a C70-Sm-C70 dimer structure.

本文言語English
ページ(範囲)177-183
ページ数7
ジャーナルChemical Physics Letters
359
3-4
DOI
出版ステータスPublished - 2002 6 20
外部発表はい

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

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