Carbon-oxygen bond activation of carboxylic anhydrides by zerovalent palladium complexes and its application to catalytic reactions

Kazuhiro Nagayama, Isao Shimizu, Akio Yamamoto

研究成果: Article

2 引用 (Scopus)

抜粋

Acyclic and cyclic carboxylic anhydrides oxidatively add to zerovalent palladium complexes having tertiary phosphines with carbon-oxygen bond cleavage to give corresponding acyl(carboxylato)palladium complexes, which subsequently react with atmospheric dihydrogen at room temperature to form aldehydes and carboxylic acids. Application of these results led us to the discovery of novel aldehyde synthesis by hydrogenation of carboxylic anhydrides catalyzed by palladium complexes. Furthermore we have developed atom-efficient and environmentally benign, direct hydrogenation of carboxylic acids to corresponding aldehydes in the presence of trimethylacetic anhydride catalyzed by palladium complexes.

元の言語English
ページ(範囲)775-783
ページ数9
ジャーナルYuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
57
発行部数9
出版物ステータスPublished - 1999

ASJC Scopus subject areas

  • Organic Chemistry

フィンガープリント Carbon-oxygen bond activation of carboxylic anhydrides by zerovalent palladium complexes and its application to catalytic reactions' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用