抄録
The catalytic asymmetric intramolecular cyclopropanation (CAIMCP) of α-diazo-α-diphenylphosphoryl acetate has been investigated. The maximum ee of the CAIMCP was 91% and the absolute configuration of the two products was successfully determined. Our previously reported model to explain the enantiofacial selectivity of the reacting alkene was successfully applied to rationalize the enantioselectivity of the CAIMCP.
本文言語 | English |
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ページ(範囲) | 541-553 |
ページ数 | 13 |
ジャーナル | Heterocycles |
巻 | 94 |
号 | 3 |
DOI | |
出版ステータス | Published - 2017 |
ASJC Scopus subject areas
- 分析化学
- 薬理学
- 有機化学