Catalytic asymmetric intramolecular cyclopropanation of α-diazo-α-phosphoryl acetate

Saori Inoue; Kotaro Nagatani; Yunosuke Hoshino; Haruka Tezuka; Nasahisa Nakada

doi:10.3987/COM-17-13656

Catalytic asymmetric intramolecular cyclopropanation of α-diazo-α-phosphoryl acetate

Saori Inoue, Kotaro Nagatani, Yunosuke Hoshino, Haruka Tezuka, Nasahisa Nakada

研究成果: Article

抜粋

The catalytic asymmetric intramolecular cyclopropanation (CAIMCP) of α-diazo-α-diphenylphosphoryl acetate has been investigated. The maximum ee of the CAIMCP was 91% and the absolute configuration of the two products was successfully determined. Our previously reported model to explain the enantiofacial selectivity of the reacting alkene was successfully applied to rationalize the enantioselectivity of the CAIMCP.

元の言語	English
ページ（範囲）	541-553
ページ数	13
ジャーナル	Heterocycles
巻	94
発行部数	3
DOI	https://doi.org/10.3987/COM-17-13656
出版物ステータス	Published - 2017

フィンガープリント

ASJC Scopus subject areas

Analytical Chemistry
Pharmacology
Organic Chemistry

これを引用

Inoue, S., Nagatani, K., Hoshino, Y., Tezuka, H., & Nakada, N. (2017). Catalytic asymmetric intramolecular cyclopropanation of α-diazo-α-phosphoryl acetate. Heterocycles, 94(3), 541-553. https://doi.org/10.3987/COM-17-13656

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AU - Nakada, Nasahisa

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文献にアクセス

10.3987/COM-17-13656