Catalytic asymmetric intramolecular cyclopropanation of α-diazo-α-phosphoryl acetate

Saori Inoue; Kotaro Nagatani; Yunosuke Hoshino; Haruka Tezuka; Nasahisa Nakada

doi:10.3987/COM-17-13656

Catalytic asymmetric intramolecular cyclopropanation of α-diazo-α-phosphoryl acetate

Saori Inoue, Kotaro Nagatani, Yunosuke Hoshino, Haruka Tezuka, Nasahisa Nakada

研究成果: Article › 査読

抄録

The catalytic asymmetric intramolecular cyclopropanation (CAIMCP) of α-diazo-α-diphenylphosphoryl acetate has been investigated. The maximum ee of the CAIMCP was 91% and the absolute configuration of the two products was successfully determined. Our previously reported model to explain the enantiofacial selectivity of the reacting alkene was successfully applied to rationalize the enantioselectivity of the CAIMCP.

本文言語	English
ページ（範囲）	541-553
ページ数	13
ジャーナル	Heterocycles
巻	94
号	3
DOI	https://doi.org/10.3987/COM-17-13656
出版ステータス	Published - 2017

ASJC Scopus subject areas

分析化学
薬理学
有機化学

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10.3987/COM-17-13656

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abstract = "The catalytic asymmetric intramolecular cyclopropanation (CAIMCP) of α-diazo-α-diphenylphosphoryl acetate has been investigated. The maximum ee of the CAIMCP was 91% and the absolute configuration of the two products was successfully determined. Our previously reported model to explain the enantiofacial selectivity of the reacting alkene was successfully applied to rationalize the enantioselectivity of the CAIMCP.",

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AU - Nakada, Nasahisa

PY - 2017

Y1 - 2017

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Catalytic asymmetric intramolecular cyclopropanation of α-diazo-α-phosphoryl acetate

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