Catalytic asymmetric intramolecular cyclopropanation of α-diazo-α-phosphoryl acetate

Saori Inoue, Kotaro Nagatani, Yunosuke Hoshino, Haruka Tezuka, Nasahisa Nakada

    研究成果: Article査読

    抄録

    The catalytic asymmetric intramolecular cyclopropanation (CAIMCP) of α-diazo-α-diphenylphosphoryl acetate has been investigated. The maximum ee of the CAIMCP was 91% and the absolute configuration of the two products was successfully determined. Our previously reported model to explain the enantiofacial selectivity of the reacting alkene was successfully applied to rationalize the enantioselectivity of the CAIMCP.

    本文言語English
    ページ(範囲)541-553
    ページ数13
    ジャーナルHeterocycles
    94
    3
    DOI
    出版ステータスPublished - 2017

    ASJC Scopus subject areas

    • 分析化学
    • 薬理学
    • 有機化学

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