Catalytic asymmetric intramolecular cyclopropanation of α-diazo-α-phosphoryl acetate

Saori Inoue, Kotaro Nagatani, Yunosuke Hoshino, Haruka Tezuka, Nasahisa Nakada

    研究成果: Article

    抜粋

    The catalytic asymmetric intramolecular cyclopropanation (CAIMCP) of α-diazo-α-diphenylphosphoryl acetate has been investigated. The maximum ee of the CAIMCP was 91% and the absolute configuration of the two products was successfully determined. Our previously reported model to explain the enantiofacial selectivity of the reacting alkene was successfully applied to rationalize the enantioselectivity of the CAIMCP.

    元の言語English
    ページ(範囲)541-553
    ページ数13
    ジャーナルHeterocycles
    94
    発行部数3
    DOI
    出版物ステータスPublished - 2017

      フィンガープリント

    ASJC Scopus subject areas

    • Analytical Chemistry
    • Pharmacology
    • Organic Chemistry

    これを引用

    Inoue, S., Nagatani, K., Hoshino, Y., Tezuka, H., & Nakada, N. (2017). Catalytic asymmetric intramolecular cyclopropanation of α-diazo-α-phosphoryl acetate. Heterocycles, 94(3), 541-553. https://doi.org/10.3987/COM-17-13656