Chameleonic layered metal-organic frameworks with variable charge-ordered states triggered by temperature and guest molecules

Jian Chen, Yoshihiro Sekine, Atsushi Okazawa, Hiroyasu Sato, Wataru Kosaka, Hitoshi Miyasaka*

*この研究の対応する著者

研究成果: Article査読

12 被引用数 (Scopus)

抄録

Molecular materials whose electronic states are multiply varied depending on external stimuli are among the most promising targets for the development of multiply accessible molecular switches. Here, we report a honeycomb layer composed of tetraoxolene-bridged iron (Fe) subunits whose charge-ordered states are multiply variable via thermal treatments and solvation/desolvation with the crystallinity intact. The compound is (NPr4)2[Fe2(Cl2An)3] (1-d; NPr4+ = tetra-n-propylammonium; Cl2An2- = 2,5-dichloro-3,6-dihydroxo-1,4-benzoquinonate), which possesses three charge-ordered states: A low-temperature (LT) phase [(Fe3+)2(Cl2An2-)(Cl2An3-)2]2-; an intermediate (IM) phase [(Fe2.5+)2(Cl2An2-)(Cl2An2.5-)2]2-; and a high-temperature (HT) phase [(Fe2+)2(Cl2An2-)3]2- that varies according to temperature. In addition, the LT phase of 1-d is reversibly changeable to another IM phase in its solvated compound 1via a solvation/desolvation process at room temperature. This example demonstrates a new multiple-switching system based on electron transfer and host-guest chemistry in a charge-flexible metal-organic framework.

本文言語English
ページ(範囲)3610-3618
ページ数9
ジャーナルChemical Science
11
14
DOI
出版ステータスPublished - 2020 4月 14
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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