Chapter 12: Organocatalyzed Step-growth Polymerization

Amaury Bossion, Katherine V. Heifferon, Nicolas Zivic, Timothy Edward Long, Haritz Sardon

研究成果: Chapter

抄録

Organocatalysis has emerged in the last few years as an important tool for polymer synthesis. Extensively used in ring-opening processes, organocompounds have recently been applied to step-growth polymerizations for the synthesis of important classes of polymers, such as polyurethanes, polycarbonates, and polyesters, as well as less explored polymers, including polyethers, polycarbonates, and polybenzoins. Organocatalysts have already been shown to be good alternatives to the more commonly used organometallics, with in some cases comparable and better activities. Some of them have also demonstrated lower toxicity and easy removal in comparison with metal catalysts, which represents clear benefits especially when employing polymers in high values and sensitive fields such as bioelectronics and biomedical. Despite their wide utilization in ring-opening polymerization, less attention has been devoted to their use in step-growth polymerizations. This chapter will highlight recent advances in organocatalysis in step-growth polymerizations and focus on the step-growth polymerization catalyzed by (1) Brønsted and Lewis bases, (2) Brønsted and Lewis acids and (3) organic ionic salts.

本文言語English
ホスト出版物のタイトルOrganic Catalysis for Polymerisation
編集者Andrew Dove, Haritz Sardon, Stefan Naumann
出版社Royal Society of Chemistry
ページ531-583
ページ数53
31
DOI
出版ステータスPublished - 2019 1 1
外部発表はい

出版物シリーズ

名前RSC Polymer Chemistry Series
番号31
2019-January
ISSN(印刷版)2044-0790
ISSN(電子版)2044-0804

ASJC Scopus subject areas

  • バイオテクノロジー
  • バイオエンジニアリング
  • 生体材料
  • ポリマーおよびプラスチック

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