Chapter 12

Organocatalyzed Step-growth Polymerization

Amaury Bossion, Katherine V. Heifferon, Nicolas Zivic, Timothy Edward Long, Haritz Sardon

研究成果: Chapter

抄録

Organocatalysis has emerged in the last few years as an important tool for polymer synthesis. Extensively used in ring-opening processes, organocompounds have recently been applied to step-growth polymerizations for the synthesis of important classes of polymers, such as polyurethanes, polycarbonates, and polyesters, as well as less explored polymers, including polyethers, polycarbonates, and polybenzoins. Organocatalysts have already been shown to be good alternatives to the more commonly used organometallics, with in some cases comparable and better activities. Some of them have also demonstrated lower toxicity and easy removal in comparison with metal catalysts, which represents clear benefits especially when employing polymers in high values and sensitive fields such as bioelectronics and biomedical. Despite their wide utilization in ring-opening polymerization, less attention has been devoted to their use in step-growth polymerizations. This chapter will highlight recent advances in organocatalysis in step-growth polymerizations and focus on the step-growth polymerization catalyzed by (1) Brønsted and Lewis bases, (2) Brønsted and Lewis acids and (3) organic ionic salts.

元の言語English
ホスト出版物のタイトルOrganic Catalysis for Polymerisation
編集者Andrew Dove, Haritz Sardon, Stefan Naumann
出版者Royal Society of Chemistry
ページ531-583
ページ数53
エディション31
DOI
出版物ステータスPublished - 2019 1 1
外部発表Yes

出版物シリーズ

名前RSC Polymer Chemistry Series
番号31
2019-January
ISSN(印刷物)2044-0790
ISSN(電子版)2044-0804

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polycarbonate
Polymerization
Polymers
Growth
Polycarbonates
Lewis Bases
Lewis Acids
Polyesters
Polyurethanes
Polyethers
Ring opening polymerization
Organometallics
Toxicity
Salts
Metals
Catalysts
Acids

ASJC Scopus subject areas

  • Biotechnology
  • Bioengineering
  • Biomaterials
  • Polymers and Plastics

これを引用

Bossion, A., Heifferon, K. V., Zivic, N., Long, T. E., & Sardon, H. (2019). Chapter 12: Organocatalyzed Step-growth Polymerization. : A. Dove, H. Sardon, & S. Naumann (版), Organic Catalysis for Polymerisation (31 版, pp. 531-583). (RSC Polymer Chemistry Series; 巻数 2019-January, 番号 31). Royal Society of Chemistry. https://doi.org/10.1039/9781788015738-00531

Chapter 12 : Organocatalyzed Step-growth Polymerization. / Bossion, Amaury; Heifferon, Katherine V.; Zivic, Nicolas; Long, Timothy Edward; Sardon, Haritz.

Organic Catalysis for Polymerisation. 版 / Andrew Dove; Haritz Sardon; Stefan Naumann. 31. 編 Royal Society of Chemistry, 2019. p. 531-583 (RSC Polymer Chemistry Series; 巻 2019-January, 番号 31).

研究成果: Chapter

Bossion, A, Heifferon, KV, Zivic, N, Long, TE & Sardon, H 2019, Chapter 12: Organocatalyzed Step-growth Polymerization. : A Dove, H Sardon & S Naumann (版), Organic Catalysis for Polymerisation. 31 Edn, RSC Polymer Chemistry Series, 番号 31, 巻. 2019-January, Royal Society of Chemistry, pp. 531-583. https://doi.org/10.1039/9781788015738-00531
Bossion A, Heifferon KV, Zivic N, Long TE, Sardon H. Chapter 12: Organocatalyzed Step-growth Polymerization. : Dove A, Sardon H, Naumann S, 編集者, Organic Catalysis for Polymerisation. 31 版 Royal Society of Chemistry. 2019. p. 531-583. (RSC Polymer Chemistry Series; 31). https://doi.org/10.1039/9781788015738-00531
Bossion, Amaury ; Heifferon, Katherine V. ; Zivic, Nicolas ; Long, Timothy Edward ; Sardon, Haritz. / Chapter 12 : Organocatalyzed Step-growth Polymerization. Organic Catalysis for Polymerisation. 編集者 / Andrew Dove ; Haritz Sardon ; Stefan Naumann. 31. 版 Royal Society of Chemistry, 2019. pp. 531-583 (RSC Polymer Chemistry Series; 31).
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