Chemical and electrochemical intercalation of a viologen into V2O5 xerogel films

Ikou Kato; Teruyuki Nakato; Kazuyuki Kuroda; Chuzo Kato

doi:10.1016/0166-6622(90)80106-E

Chemical and electrochemical intercalation of a viologen into V₂O₅ xerogel films

Ikou Kato, Teruyuki Nakato, Kazuyuki Kuroda, Chuzo Kato^*

^*この研究の対応する著者

先進理工学部

研究成果: Article › 査読

11 被引用数 (Scopus)

抄録

Heptylviologen was intercalated into V₂O₅ xerogel films by chemical and electrochemical methods. Chemical intercalation occurred by the reaction of a V₂O₅ xerogel film with a propylene carbonate (PC) solution of heptylviologen (HV). The viologen was present as a solvated form in the interlayer of V₂O₅ gel. A reversible intercalation-deintercalation of HV was carried out by electrochemical reduction-oxidation of the V₂O₅ xerogel film in a PC solution of HV. The electrochemical intercalation took place only when the interlayer region of V₂O₅ gel was expanded by PC.

本文言語	English
ページ（範囲）	241-245
ページ数	5
ジャーナル	Colloids and Surfaces
巻	49
号	C
DOI	https://doi.org/10.1016/0166-6622(90)80106-E
出版ステータス	Published - 1990

ASJC Scopus subject areas

工学（全般）

文献へのアクセス

10.1016/0166-6622(90)80106-E

他のファイルとリンク

引用スタイル

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abstract = "Heptylviologen was intercalated into V2O5 xerogel films by chemical and electrochemical methods. Chemical intercalation occurred by the reaction of a V2O5 xerogel film with a propylene carbonate (PC) solution of heptylviologen (HV). The viologen was present as a solvated form in the interlayer of V2O5 gel. A reversible intercalation-deintercalation of HV was carried out by electrochemical reduction-oxidation of the V2O5 xerogel film in a PC solution of HV. The electrochemical intercalation took place only when the interlayer region of V2O5 gel was expanded by PC.",

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Y1 - 1990

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AB - Heptylviologen was intercalated into V2O5 xerogel films by chemical and electrochemical methods. Chemical intercalation occurred by the reaction of a V2O5 xerogel film with a propylene carbonate (PC) solution of heptylviologen (HV). The viologen was present as a solvated form in the interlayer of V2O5 gel. A reversible intercalation-deintercalation of HV was carried out by electrochemical reduction-oxidation of the V2O5 xerogel film in a PC solution of HV. The electrochemical intercalation took place only when the interlayer region of V2O5 gel was expanded by PC.

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