Chemistry of monoorganopalladium complexes relevant to catalysis

Akio Yamamoto, Yoshihito Kayaki, Kazuhiro Nagayama, Isao Shimizu

研究成果: Article

46 被引用数 (Scopus)

抄録

Neutral and cationic organopalladium complexes have been prepared as models for active intermediates involved in palladium-catalyzed reactions. Comparison of the reactivities of the neutral and cationic complexes revealed the much higher reactivities of the latter toward β-elimination and olefin or CO insertion. Generation of the solvent-coordinated hemilabile site on the cationic organopalladium complexes was indicated as a dominant factor in enhancing the reactivities. Utilizing the reactivity of an acylpalladium complex toward hydrogen, a novel, selective, and environmentally benign hydrogenation process catalyzed by palladium complexes to give various aldehydes has been developed.

本文言語English
ページ(範囲)925-937
ページ数13
ジャーナルSynlett
7
出版ステータスPublished - 2000

ASJC Scopus subject areas

  • Organic Chemistry

フィンガープリント 「Chemistry of monoorganopalladium complexes relevant to catalysis」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル