抄録
Chiral catalytic activities of electrode surfaces fabricated by magnetoelectrochemical etching without oxygen adsorption in a vertical magnetohydrodynamic (MHD) flow have been theoretically examined. Then, the following points were clarified: under anionic specific adsorption, such activities arise from the screw dislocations of 2D pits. Their chirality is donated by microscopic vortexes termed micro-MHD flows, which are formed on the free surfaces covered with ionic vacancies. As a result, under upward (+) and downward (-) magnetic fields, D (dextrorotatory)- and L (levorotatory)-activities appear, respectively.
元の言語 | English |
---|---|
ページ(範囲) | 353-360 |
ページ数 | 8 |
ジャーナル | Magnetohydrodynamics |
巻 | 51 |
発行部数 | 2 |
出版物ステータス | Published - 2015 |
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ASJC Scopus subject areas
- Electrical and Electronic Engineering
- Physics and Astronomy(all)
これを引用
Chiral catalytic activities in magnetoelectrochemical etching. / Aogaki, R.; Morimoto, R.; Asanuma, M.; Mogi, I.; Sugiyama, A.; Miura, M.; Oshikiri, Y.; Yamauchi, Y.
:: Magnetohydrodynamics, 巻 51, 番号 2, 2015, p. 353-360.研究成果: Article
}
TY - JOUR
T1 - Chiral catalytic activities in magnetoelectrochemical etching
AU - Aogaki, R.
AU - Morimoto, R.
AU - Asanuma, M.
AU - Mogi, I.
AU - Sugiyama, A.
AU - Miura, M.
AU - Oshikiri, Y.
AU - Yamauchi, Y.
PY - 2015
Y1 - 2015
N2 - Chiral catalytic activities of electrode surfaces fabricated by magnetoelectrochemical etching without oxygen adsorption in a vertical magnetohydrodynamic (MHD) flow have been theoretically examined. Then, the following points were clarified: under anionic specific adsorption, such activities arise from the screw dislocations of 2D pits. Their chirality is donated by microscopic vortexes termed micro-MHD flows, which are formed on the free surfaces covered with ionic vacancies. As a result, under upward (+) and downward (-) magnetic fields, D (dextrorotatory)- and L (levorotatory)-activities appear, respectively.
AB - Chiral catalytic activities of electrode surfaces fabricated by magnetoelectrochemical etching without oxygen adsorption in a vertical magnetohydrodynamic (MHD) flow have been theoretically examined. Then, the following points were clarified: under anionic specific adsorption, such activities arise from the screw dislocations of 2D pits. Their chirality is donated by microscopic vortexes termed micro-MHD flows, which are formed on the free surfaces covered with ionic vacancies. As a result, under upward (+) and downward (-) magnetic fields, D (dextrorotatory)- and L (levorotatory)-activities appear, respectively.
UR - http://www.scopus.com/inward/record.url?scp=84938923892&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84938923892&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:84938923892
VL - 51
SP - 353
EP - 360
JO - Magnetohydrodynamics
JF - Magnetohydrodynamics
SN - 0024-998X
IS - 2
ER -