抄録
Enantioselective intramolecular cycloaddition of hexaynes with 1,3-diyne moiety was examined. Chiral Rh catalyst provided axially chiral 1,1′ -bis(biphenylenyl) derivatives by consecutive [2+2+2] cycloaddition. In contrast, chiral Ir catalyst provided axially chiral macrocyclic compounds with 1,3-diyne moiety by single [2+2+2] cycloaddition.
本文言語 | English |
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ページ(範囲) | 363-370 |
ページ数 | 8 |
ジャーナル | Heteroatom Chemistry |
巻 | 22 |
号 | 3-4 |
DOI | |
出版ステータス | Published - 2011 |
ASJC Scopus subject areas
- 化学 (全般)