Chirality sensing by nonchiral porphines

Jan Labuta; Shinsuke Ishihara; Atsuomi Shundo; Satoshi Arai; Shinji Takeoka; Katsuhiko Ariga; Jonathan P. Hill

doi:10.1002/chem.201100052

Chirality sensing by nonchiral porphines

Jan Labuta, Shinsuke Ishihara, Atsuomi Shundo, Satoshi Arai, Shinji Takeoka, Katsuhiko Ariga, Jonathan P. Hill

先進理工学部

研究成果: Article

28 引用（Scopus）

抜粋

Let's split the difference: Nonchiral porphine macrocycles have been used as chemical shift agents for the determination of the enantiomeric excesses of chiral carboxylic acids. This method is based on the observation of the relative splitting induced in the ¹H NMR resonances of the porphine protons. A mechanism for the recognition based on the fast exchange of the guest molecules has been proposed (see scheme).

元の言語	English
ページ（範囲）	3558-3561
ページ数	4
ジャーナル	Chemistry - A European Journal
巻	17
発行部数	13
DOI	https://doi.org/10.1002/chem.201100052
出版物ステータス	Published - 2011 3 21

ASJC Scopus subject areas

Catalysis
Organic Chemistry

文献にアクセス

10.1002/chem.201100052

フィンガープリント Chirality sensing by nonchiral porphines' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

これを引用

Labuta, J., Ishihara, S., Shundo, A., Arai, S., Takeoka, S., Ariga, K., & Hill, J. P. (2011). Chirality sensing by nonchiral porphines. Chemistry - A European Journal, 17(13), 3558-3561. https://doi.org/10.1002/chem.201100052

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AU - Arai, Satoshi

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AU - Ariga, Katsuhiko

AU - Hill, Jonathan P.

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