Chirality sensing by nonchiral porphines

Jan Labuta, Shinsuke Ishihara, Atsuomi Shundo, Satoshi Arai, Shinji Takeoka, Katsuhiko Ariga, Jonathan P. Hill

研究成果: Article

28 引用 (Scopus)

抜粋

Let's split the difference: Nonchiral porphine macrocycles have been used as chemical shift agents for the determination of the enantiomeric excesses of chiral carboxylic acids. This method is based on the observation of the relative splitting induced in the 1H NMR resonances of the porphine protons. A mechanism for the recognition based on the fast exchange of the guest molecules has been proposed (see scheme).

元の言語English
ページ(範囲)3558-3561
ページ数4
ジャーナルChemistry - A European Journal
17
発行部数13
DOI
出版物ステータスPublished - 2011 3 21

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

フィンガープリント Chirality sensing by nonchiral porphines' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用

    Labuta, J., Ishihara, S., Shundo, A., Arai, S., Takeoka, S., Ariga, K., & Hill, J. P. (2011). Chirality sensing by nonchiral porphines. Chemistry - A European Journal, 17(13), 3558-3561. https://doi.org/10.1002/chem.201100052