Communication - Hydrogen peroxide reduction in aqueous electrolytes

Influence of a heterogeneous decomposition step

Nicholas S. Georgescu, Daniel Alberto Scherson

研究成果: Article

1 引用 (Scopus)

抄録

A mechanistic model is herein presented for the reduction of H2O2(aq) in aqueous electrolytes on a rotating disk electrode that considers the possible heterogeneous dismutation of H2O2(aq). A theoretical analysis of this model predicts Koutecky-Levich plots that deviate from linearity at high rotation rates depending on the relative values of the rates constants of the processes involved, in agreement with the behavior found for a variety of electrode materials.

元の言語English
ページ(範囲)H630-H632
ジャーナルJournal of the Electrochemical Society
163
発行部数8
DOI
出版物ステータスPublished - 2016 1 1
外部発表Yes

Fingerprint

Hydrogen peroxide
Hydrogen Peroxide
Electrolytes
Decomposition
Electrodes
Communication
Rotating disks
Rate constants

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

これを引用

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