Conjugated poly-p-phenylene (PPP) from poly(m-cyclohexadiene) (PCHD) homo- and block copolymers: controlled processability and properties

J. Mays*, K. Hong, Y. Wang, R. C. Advincula

*この研究の対応する著者

研究成果: Article査読

4 被引用数 (Scopus)

抄録

Conjugated polymers have been used as solid-state materials for a variety of opto-electronic applications. Thus, their processability in a number of device fabrication protocols is an important consideration. In this report, we indicate our results on the synthesis of conjugated poly-p-phenylene (PPP) materials derived from poly(1,3-cyclohexadiene) (PCHD). The precursor PCHD polymers were synthesized by living anionic polymerization to produce homoand block copolymer configurations with polystyrene. We have used a variety of initiators, solvent, and temperature conditions to determine the right parameters for obtaining narrow MWD polymers. The conditions for polymerization determined the ratio of 1,2 and 1,4 isomers in the microstructure. We then proceeded with conversion to PPP derivatives using a dehydrogenation reaction with chloranil. Our results indicate a systematic conversion to a conjugated polymer with increased solubility and photoluminescence properties. The microstructure, MW and block copolymer composition affecting the processability and conversion properties dramatically.

本文言語English
ページ(範囲)189-194
ページ数6
ジャーナルMaterials Research Society Symposium - Proceedings
561
出版ステータスPublished - 1999
外部発表はい

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料

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