Consecutive HDDA and TDDA reactions of silicon-tethered tetraynes for the synthesis of dibenzosilole-fused polycyclic compounds and their unique reactivity

Akihito Mitake, Rikako Nagai, Ayato Sekine, Hideaki Takano, Natsuhiko Sugimura, Kyalo Stephen Kanyiva, Takanori Shibata

研究成果: Article査読

4 被引用数 (Scopus)

抄録

Silicon-tethered tetraynes possessing a 1,3-diyne moiety underwent consecutive hexadehydro- and tetradehydro-Diels-Alder reactions to give a series of fused polycyclic aromatic compounds containing a dibenzosilole skeleton. The benzene ring in the product acted as a 1,3-diene and reacted with the active alkyne as well as oxygen to provide [4 + 2] cycloadducts.

本文言語English
ページ(範囲)6715-6720
ページ数6
ジャーナルChemical Science
10
27
DOI
出版ステータスPublished - 2019

ASJC Scopus subject areas

  • Chemistry(all)

フィンガープリント 「Consecutive HDDA and TDDA reactions of silicon-tethered tetraynes for the synthesis of dibenzosilole-fused polycyclic compounds and their unique reactivity」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル