Consecutive HDDA and TDDA reactions of silicon-tethered tetraynes for the synthesis of dibenzosilole-fused polycyclic compounds and their unique reactivity

Akihito Mitake, Rikako Nagai, Ayato Sekine, Hideaki Takano, Natsuhiko Sugimura, Stephen Kyalo Kanyiva, Takanori Shibata

研究成果: Article

抄録

Silicon-tethered tetraynes possessing a 1,3-diyne moiety underwent consecutive hexadehydro- and tetradehydro-Diels-Alder reactions to give a series of fused polycyclic aromatic compounds containing a dibenzosilole skeleton. The benzene ring in the product acted as a 1,3-diene and reacted with the active alkyne as well as oxygen to provide [4 + 2] cycloadducts.

元の言語English
ページ(範囲)6715-6720
ページ数6
ジャーナルChemical Science
10
発行部数27
DOI
出版物ステータスPublished - 2019 1 1

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Polycyclic Compounds
Alkynes
Aromatic compounds
Silicon
Benzene
Oxygen

ASJC Scopus subject areas

  • Chemistry(all)

これを引用

Consecutive HDDA and TDDA reactions of silicon-tethered tetraynes for the synthesis of dibenzosilole-fused polycyclic compounds and their unique reactivity. / Mitake, Akihito; Nagai, Rikako; Sekine, Ayato; Takano, Hideaki; Sugimura, Natsuhiko; Kanyiva, Stephen Kyalo; Shibata, Takanori.

:: Chemical Science, 巻 10, 番号 27, 01.01.2019, p. 6715-6720.

研究成果: Article

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AU - Takano, Hideaki

AU - Sugimura, Natsuhiko

AU - Kanyiva, Stephen Kyalo

AU - Shibata, Takanori

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