Consolidation of Sm2Fe17N3 magnets with Sm-based eutectic alloy binder

Kohei Otogawa, Kenta Takagi*, Toru Asahi

*この研究の対応する著者

    研究成果: Article査読

    7 被引用数 (Scopus)

    抄録

    Consolidation of Sm2Fe17N3 powder with a new Sm-based alloy as a metal binder was examined. Investigation of various Sm-based alloys led to the discovery of a Sm-Fe-Cu-Al alloy having a low melting point of 495 °C, which is more than 100 °C lower than the thermal decomposition temperature of Sm2Fe17N3. The metallographic structure of the Sm-Fe-Cu-Al alloy ingot was a SmCu/Sm eutectic structure containing solid-solution Fe, Cu and Al. Pulverized Sm-Fe-Cu-Al powder as a binder was mixed with Sm2Fe17N3 powder, and the mixture was hot-pressed by a current sintering apparatus. The Sm-Fe-Cu-Al alloy binder did not affect the magnetization of Sm2Fe17N3 adversely after consolidation. The binder-added Sm2Fe17N3 hot-pressed compacts successfully maintained the coercivity of the raw powder over a wide range of hot-pressing temperatures, whereas additive-free Sm2Fe17N3 hot-pressed compacts showed a significant decrease in coercivity. Therefore, the Sm-Fe-Cu-Al alloy binder overcame the weakest point of Sm2Fe17N3 magnets. XRD analysis suggested that the Sm-Fe-Cu-Al binder restrained precipitation of the α-Fe phase, which is thought to be the probable cause the decrease of coercivity.

    本文言語English
    ページ(範囲)19-26
    ページ数8
    ジャーナルJournal of Alloys and Compounds
    746
    DOI
    出版ステータスPublished - 2018 5 25

    ASJC Scopus subject areas

    • 材料力学
    • 機械工学
    • 金属および合金
    • 材料化学

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