Construction of a Polycyclic Conjugated System Containing a Dibenzazepine Moiety by Cationic Gold(I)-Catalyzed Cycloisomerization

Mamoru Ito, Ryosuke Kawasaki, Kyalo Stephen Kanyiva, Takanori Shibata

研究成果: Article査読

10 被引用数 (Scopus)

抄録

A new π-conjugated system of nitrogen-containing polycyclic compounds was constructed by cationic AuI-catalyzed cycloisomerization. Intramolecular reaction of 9-(2-alkynylphenyl)-9H-carbazole derivatives gave a variety of penta- and hexacyclic compounds possessing a dibenzazepine skeleton. The rigid carbazole structure was responsible for efficient 7-endo-dig cycloisomerization.

本文言語English
ページ(範囲)5234-5237
ページ数4
ジャーナルEuropean Journal of Organic Chemistry
2016
31
DOI
出版ステータスPublished - 2016 11

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 有機化学

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