Controlled growth for synthesizing a compact mordenite membrane

Masahiko Matsukata*, Ken ichi Sawamura, Tsutomu Shirai, Mitsuko Takada, Yasushi Sekine, Eiichi Kikuchi

*この研究の対応する著者

研究成果: Article査読

27 被引用数 (Scopus)

抄録

Controlling the growth of zeolite crystals on a porous alumina support is essential for preparing a compact zeolite membarne. First, mordenite seed crystals applied on a nonporous α-alumina disk were grown and morphological change of mordenite crystals were observed in the course of growth. Then, mordenite membranes were synthesized on a porous α-alumina tube under the same conditions employed in the study using the alumina disks. We found that seed crystal growth was widely controllable by changing water content in reaction solution, which resulted in better control of the morphology of mordenite crystals for synthesizing a thin compact mordenite membrane. Separation properties for mordenite membranes were studied in water-hydrogen binary system at 473 K with 10 kPa of water partial pressure, where no capillary condensation was expected in non-zeolitic pores. Separation factor for a mordenite membrane with a few defects was poor; however, a defect-free mordenite membrane prepared under a suitable condition highly separated steam from hydrogen.

本文言語English
ページ(範囲)18-27
ページ数10
ジャーナルJournal of Membrane Science
316
1-2
DOI
出版ステータスPublished - 2008 5月 15

ASJC Scopus subject areas

  • 生化学
  • 材料科学(全般)
  • 物理化学および理論化学
  • ろ過および分離

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