Coordination and adsorption of acetylene in the poly[(vinylcyclopentadienyl)manganese] membrane

Hiroyoshi Kawakami*, Kenji Tsuda, Hiroyuki Nishide, Eishun Tsuchida

*この研究の対応する著者

研究成果: Article査読

2 被引用数 (Scopus)

抄録

A copolymer of (vinylcyclopentadienyl)dicarbonylmanganese (CpMn) and octyl methacrylate forms its acetylene-coordinated complex reversibly and stably in the solvent-free membrane state. Kinetic and equilibrium constants of the acetylene coordination to the CpMn residue in the copolymer membrane are determined spectroscopically in situ. The acetylene coordination parameters are much smaller than those of the corresponding nitrogen coordination. Acetylene transport for the membrane is expected to be selectively augmented due to the coordination of acetylene to the fixed CpMn. However, acetylene transport behavior is in accordance with total immobilization of acetylene on the CpMn residue in the acetylene permeation through the membrane.

本文言語English
ページ(範囲)3310-3313
ページ数4
ジャーナルMacromolecules
24
11
出版ステータスPublished - 1991 1月 1

ASJC Scopus subject areas

  • 材料化学

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