抜粋
A copolymer of (vinylcyclopentadienyl)dicarbonylmanganese (CpMn) and octyl methacrylate forms its acetylene-coordinated complex reversibly and stably in the solvent-free membrane state. Kinetic and equilibrium constants of the acetylene coordination to the CpMn residue in the copolymer membrane are determined spectroscopically in situ. The acetylene coordination parameters are much smaller than those of the corresponding nitrogen coordination. Acetylene transport for the membrane is expected to be selectively augmented due to the coordination of acetylene to the fixed CpMn. However, acetylene transport behavior is in accordance with total immobilization of acetylene on the CpMn residue in the acetylene permeation through the membrane.
| 元の言語 | English |
|---|---|
| ページ（範囲） | 3310-3313 |
| ページ数 | 4 |
| ジャーナル | Macromolecules |
| 巻 | 24 |
| 発行部数 | 11 |
| 出版物ステータス | Published - 1991 1 1 |
ASJC Scopus subject areas
- Materials Chemistry
フィンガープリント Coordination and adsorption of acetylene in the poly[(vinylcyclopentadienyl)manganese] membrane' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。
これを引用
Kawakami, H., Tsuda, K., Nishide, H., & Tsuchida, E. (1991). Coordination and adsorption of acetylene in the poly[(vinylcyclopentadienyl)manganese] membrane. Macromolecules, 24(11), 3310-3313.