Coordination and adsorption of acetylene in the poly[(vinylcyclopentadienyl)manganese] membrane

Hiroyoshi Kawakami, Kenji Tsuda, Hiroyuki Nishide, Eishun Tsuchida

研究成果: Article

2 引用 (Scopus)

抜粋

A copolymer of (vinylcyclopentadienyl)dicarbonylmanganese (CpMn) and octyl methacrylate forms its acetylene-coordinated complex reversibly and stably in the solvent-free membrane state. Kinetic and equilibrium constants of the acetylene coordination to the CpMn residue in the copolymer membrane are determined spectroscopically in situ. The acetylene coordination parameters are much smaller than those of the corresponding nitrogen coordination. Acetylene transport for the membrane is expected to be selectively augmented due to the coordination of acetylene to the fixed CpMn. However, acetylene transport behavior is in accordance with total immobilization of acetylene on the CpMn residue in the acetylene permeation through the membrane.

元の言語English
ページ(範囲)3310-3313
ページ数4
ジャーナルMacromolecules
24
発行部数11
出版物ステータスPublished - 1991 1 1

ASJC Scopus subject areas

  • Materials Chemistry

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  • これを引用

    Kawakami, H., Tsuda, K., Nishide, H., & Tsuchida, E. (1991). Coordination and adsorption of acetylene in the poly[(vinylcyclopentadienyl)manganese] membrane. Macromolecules, 24(11), 3310-3313.