Coordination Isomers of Trinuclear Pt2Hg Complex That Differ in Type of Metal-Metal Bond

Tadashi Yamaguchi, Kohei Yoshiya

研究成果: Article

抄録

New type isomers that differ in metal-metal bond type are isolated. One is the Pt-Hg-Pt complex, which has two metal-metal covalent bonds, Pt-Hg = 2.5459(8) and 2.5483(7) Å, and the other is the Pt→Hg-Pt complex, which has one metal-metal covalent bond, Pt-Hg = 2.5744(6) Å, and one metal-metal dative bond, Pt→Hg = 2.6635(7) Å.

元の言語English
ページ(範囲)9548-9552
ページ数5
ジャーナルInorganic Chemistry
58
発行部数15
DOI
出版物ステータスPublished - 2019 8 5

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Isomers
isomers
Metals
metals
Covalent bonds
covalent bonds

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

これを引用

Coordination Isomers of Trinuclear Pt2Hg Complex That Differ in Type of Metal-Metal Bond. / Yamaguchi, Tadashi; Yoshiya, Kohei.

:: Inorganic Chemistry, 巻 58, 番号 15, 05.08.2019, p. 9548-9552.

研究成果: Article

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abstract = "New type isomers that differ in metal-metal bond type are isolated. One is the Pt-Hg-Pt complex, which has two metal-metal covalent bonds, Pt-Hg = 2.5459(8) and 2.5483(7) {\AA}, and the other is the Pt→Hg-Pt complex, which has one metal-metal covalent bond, Pt-Hg = 2.5744(6) {\AA}, and one metal-metal dative bond, Pt→Hg = 2.6635(7) {\AA}.",
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AB - New type isomers that differ in metal-metal bond type are isolated. One is the Pt-Hg-Pt complex, which has two metal-metal covalent bonds, Pt-Hg = 2.5459(8) and 2.5483(7) Å, and the other is the Pt→Hg-Pt complex, which has one metal-metal covalent bond, Pt-Hg = 2.5744(6) Å, and one metal-metal dative bond, Pt→Hg = 2.6635(7) Å.

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