Coordination structure and magnetic property of poly(pyridilenemethylidenenitriloiron)s

Hiroyuki Nishide, Naoki Yoshioka, Eishun Tsuchida, Hidenari Inoue

研究成果: Article

9 引用 (Scopus)

抜粋

Poly[bis(2,6-pyridinediylmethylidenenitrilohexamethylidene)iron sulfate] was said to be a ferromagnetic compound by earlier investigators. This polymer and its derivatives are carefully reprepared and their unusual magnetic property is reinvestigated spectroscopically. The counter anion species and spacer length of the polymers affect their coordination structure and magnetism. Mossbauer spectroscopy and x-ray diffractometry on the polymers indicate that their unusual magnetic property is caused by the ferromagnetic iron oxide slightly formed in the polymers.

元の言語English
ページ(範囲)497-505
ページ数9
ジャーナルJournal of Polymer Science, Part A: Polymer Chemistry
27
発行部数2
DOI
出版物ステータスPublished - 1989

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

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