Covalent fixation of the cyclic tetramer of a metallo-porphyrin based on self-complementary quadruple hydrogen bonding

Haruki Ohkawa, Akihiro Takayama, Satoshi Nakajima, Hiroyuki Nishide

研究成果: Article査読

1 被引用数 (Scopus)

抄録

The stability of quadruple hydrogen bonding in the cyclic tetramer of a metallo-porphyrin before and after a covalent fixation was investigated. According to competition and energy-transfer experiments, the exchange reaction between the cyclic tetramers of the metallo-porphyrin was fully suppressed by the covalent fixation. This spontaneous cyclization-covalent fixation strategy based on olefin metathesis can open the way to the use of cyclic assemblies in a solid phase.

本文言語English
ページ(範囲)1076-1077
ページ数2
ジャーナルChemistry Letters
35
9
DOI
出版ステータスPublished - 2006 9 5

ASJC Scopus subject areas

  • 化学 (全般)

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