抄録
The stability of quadruple hydrogen bonding in the cyclic tetramer of a metallo-porphyrin before and after a covalent fixation was investigated. According to competition and energy-transfer experiments, the exchange reaction between the cyclic tetramers of the metallo-porphyrin was fully suppressed by the covalent fixation. This spontaneous cyclization-covalent fixation strategy based on olefin metathesis can open the way to the use of cyclic assemblies in a solid phase.
本文言語 | English |
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ページ(範囲) | 1076-1077 |
ページ数 | 2 |
ジャーナル | Chemistry Letters |
巻 | 35 |
号 | 9 |
DOI | |
出版ステータス | Published - 2006 9月 5 |
ASJC Scopus subject areas
- 化学 (全般)