Cross coupling between sp 3-carbon and sp 3-carbon using a diborylmethane derivative at room temperature

Kohei Endo*, Takahiro Ohkubo, Takafumi Ishioka, Takanori Shibata

*この研究の対応する著者

研究成果: Article査読

77 被引用数 (Scopus)

抄録

A novel example of the Suzuki-Miyaura cross-coupling reaction between sp 3-carbon and sp 3-carbon is described. The reaction of a diborylmethane derivative with allyl halides or benzyl halides proceeded efficiently in the presence of appropriate Pd-catalysts at room temperature. The present approaches provide functionalized homoallylboronates and alkylboronates with excellent regio- and chemoselectivities.

本文言語English
ページ(範囲)4826-4831
ページ数6
ジャーナルJournal of Organic Chemistry
77
10
DOI
出版ステータスPublished - 2012 5 18

ASJC Scopus subject areas

  • 有機化学

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