Crystal structure of the pivalamidato-bridged platinum(II) dinuclear complex having equatorial α-pyridonate and dimethylsulfoxide ligands, [PtII 2(NH3)2(α-pyridonato)(dmso)(μ-(CH3)3CCONH)2](ClO4)

Saiko Arai, Masahiko Ochiai, Koji Ishihara, Kazuko Matsumoto

    研究成果: Article

    抄録

    A pivalamidato-bridged platinum(II) dinuclear complex having equatorial dimethylsulfoxide (dmso) ligands, [PtII 2(NH3)2(dmso)2(μ-(CH3)3CCONH)2](ClO4)2 (1) as well as the title complex, [PtII 2(NH3)2(α-pyridonato)(dmso)(μ- (CH3)3CCONH)2](ClO4) (2), were structurally characterized by single-crystal X-ray analysis. Although in 2, the oxygen atom of the dmso ligand is oriented to the ammine ligand to make a stable hydrogen bond, such a short hydrogen bond is not observed for either of the dmso ligands in 1. This seems to be due to a steric hindrance between the dmso ligands. 2007

    元の言語English
    ジャーナルAnalytical Sciences: X-ray Structure Analysis Online
    23
    発行部数3
    出版物ステータスPublished - 2007

    Fingerprint

    Dimethyl Sulfoxide
    Platinum
    Crystal structure
    Ligands
    Hydrogen bonds
    X ray analysis
    perchlorate
    Single crystals
    Atoms
    Oxygen

    ASJC Scopus subject areas

    • Analytical Chemistry
    • Materials Chemistry

    これを引用

    @article{b62f1bf35265491ebba3ace9c7359088,
    title = "Crystal structure of the pivalamidato-bridged platinum(II) dinuclear complex having equatorial α-pyridonate and dimethylsulfoxide ligands, [PtII 2(NH3)2(α-pyridonato)(dmso)(μ-(CH3)3CCONH)2](ClO4)",
    abstract = "A pivalamidato-bridged platinum(II) dinuclear complex having equatorial dimethylsulfoxide (dmso) ligands, [PtII 2(NH3)2(dmso)2(μ-(CH3)3CCONH)2](ClO4)2 (1) as well as the title complex, [PtII 2(NH3)2(α-pyridonato)(dmso)(μ- (CH3)3CCONH)2](ClO4) (2), were structurally characterized by single-crystal X-ray analysis. Although in 2, the oxygen atom of the dmso ligand is oriented to the ammine ligand to make a stable hydrogen bond, such a short hydrogen bond is not observed for either of the dmso ligands in 1. This seems to be due to a steric hindrance between the dmso ligands. 2007",
    author = "Saiko Arai and Masahiko Ochiai and Koji Ishihara and Kazuko Matsumoto",
    year = "2007",
    language = "English",
    volume = "23",
    journal = "Analytical Sciences: X-ray Structure Analysis Online",
    issn = "1348-2238",
    publisher = "Japan Society for Analytical Chemistry",
    number = "3",

    }

    TY - JOUR

    T1 - Crystal structure of the pivalamidato-bridged platinum(II) dinuclear complex having equatorial α-pyridonate and dimethylsulfoxide ligands, [PtII 2(NH3)2(α-pyridonato)(dmso)(μ-(CH3)3CCONH)2](ClO4)

    AU - Arai, Saiko

    AU - Ochiai, Masahiko

    AU - Ishihara, Koji

    AU - Matsumoto, Kazuko

    PY - 2007

    Y1 - 2007

    N2 - A pivalamidato-bridged platinum(II) dinuclear complex having equatorial dimethylsulfoxide (dmso) ligands, [PtII 2(NH3)2(dmso)2(μ-(CH3)3CCONH)2](ClO4)2 (1) as well as the title complex, [PtII 2(NH3)2(α-pyridonato)(dmso)(μ- (CH3)3CCONH)2](ClO4) (2), were structurally characterized by single-crystal X-ray analysis. Although in 2, the oxygen atom of the dmso ligand is oriented to the ammine ligand to make a stable hydrogen bond, such a short hydrogen bond is not observed for either of the dmso ligands in 1. This seems to be due to a steric hindrance between the dmso ligands. 2007

    AB - A pivalamidato-bridged platinum(II) dinuclear complex having equatorial dimethylsulfoxide (dmso) ligands, [PtII 2(NH3)2(dmso)2(μ-(CH3)3CCONH)2](ClO4)2 (1) as well as the title complex, [PtII 2(NH3)2(α-pyridonato)(dmso)(μ- (CH3)3CCONH)2](ClO4) (2), were structurally characterized by single-crystal X-ray analysis. Although in 2, the oxygen atom of the dmso ligand is oriented to the ammine ligand to make a stable hydrogen bond, such a short hydrogen bond is not observed for either of the dmso ligands in 1. This seems to be due to a steric hindrance between the dmso ligands. 2007

    UR - http://www.scopus.com/inward/record.url?scp=70450260818&partnerID=8YFLogxK

    UR - http://www.scopus.com/inward/citedby.url?scp=70450260818&partnerID=8YFLogxK

    M3 - Article

    AN - SCOPUS:70450260818

    VL - 23

    JO - Analytical Sciences: X-ray Structure Analysis Online

    JF - Analytical Sciences: X-ray Structure Analysis Online

    SN - 1348-2238

    IS - 3

    ER -