Crystal structure of the pivalamidato-bridged platinum(II) dinuclear complex having equatorial α-pyridonate and dimethylsulfoxide ligands, [PtII2(NH3)2(α-pyridonato)(dmso)(μ-(CH3)3CCONH)2](ClO4)

Saiko Arai, Masahiko Ochiai, Koji Ishihara, Kazuko Matsumoto

研究成果: Comment/debate査読

抄録

A pivalamidato-bridged platinum(II) dinuclear complex having equatorial dimethylsulfoxide (dmso) ligands, [PtII2(NH3)2(dmso)2(μ-(CH3)3CCONH)2](ClO4)2 (1) as well as the title complex, [PtII2(NH3)2(α-pyridonato)(dmso)(μ- (CH3)3CCONH)2](ClO4) (2), were structurally characterized by single-crystal X-ray analysis. Although in 2, the oxygen atom of the dmso ligand is oriented to the ammine ligand to make a stable hydrogen bond, such a short hydrogen bond is not observed for either of the dmso ligands in 1. This seems to be due to a steric hindrance between the dmso ligands. 2007

本文言語English
ページ(範囲)x43-x44
ジャーナルAnalytical Sciences: X-ray Structure Analysis Online
23
3
DOI
出版ステータスPublished - 2007

ASJC Scopus subject areas

  • 分析化学
  • 材料化学

フィンガープリント

「Crystal structure of the pivalamidato-bridged platinum(II) dinuclear complex having equatorial α-pyridonate and dimethylsulfoxide ligands, [Pt<sup>II</sup><sub>2</sub>(NH<sub>3</sub>)<sub>2</sub>(α-pyridonato)(dmso)(μ-(CH<sub>3</sub>)<sub>3</sub>CCONH)<sub>2</sub>](ClO<sub>4</sub>)」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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