Crystal structures of dimeric manganese(III) complexes of tetradentate Schiff-base ligands with ancillary axial donors

Kenichi Oyaizu, Takeshi Nakagawa, Eishun Tsuchida

研究成果: Article査読

16 被引用数 (Scopus)

抄録

[N,N'-Ethylenebis(salicylideneaminato)]manganese(III) benzoate ([Mn(salen)(O2CC6H5)] crystallized to form a solid-state dimer in which the Mn(salen) moiety is linked to its neighbor by two shared phenolate oxygen atoms, in striking contrast to the linear polymeric structure formed with bridging acetate ligands. A substantial cavity between the two manganese atoms was then produced by the weak coordination of the phenolate oxygen to the neighboring manganese bearing benzoate in a monodentate mode. (C) 2000 Elsevier Science S.A.

本文言語English
ページ(範囲)184-188
ページ数5
ジャーナルInorganica Chimica Acta
305
2
DOI
出版ステータスPublished - 2000 7 28

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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