Raman measurements in YBa2Cu3Ox (x = 6.72-6.82) high-Tc superconductors reveal intense phonon scattering due to an electronic resonance localized near oxygen vacancies on the CuO chains. Below room temperature the resonance can be photobleached in a manner similar to reported persistent photoinduced superconductivity effects, indicating photon-assisted oxygen ordering or electron vacancy capture. By comparing Raman and x-ray diffraction data we establish a correlation between the stability of the photoinduced state and the oxygen-ordering kinetics in the CuO chains.
|ジャーナル||Physical Review B - Condensed Matter and Materials Physics|
|出版物ステータス||Published - 1998 6 1|
ASJC Scopus subject areas
- Condensed Matter Physics