Decakis(phenylthio)benzophenone: A representative of a novel class of host molecule comprised of two linked persubstituted aromatic cores

Robert K. Henderson, David D. MacNicol*, Kirsty L. McCormack, Stuart J. Rowan, Dmitrii S. Yufit

*この研究の対応する著者

研究成果: Article査読

4 被引用数 (Scopus)

抄録

The title compound 1, prepared by reaction of decafluorobenzophenone 5 with PhSNa in DMEU, forms a 1:1 adduct with DMF; in this adduct the molecule's central V-shaped twin core possesses approximate C2 symmetry, though this does not extend to the molecular periphery owing to the ababababab side-chain orientational distribution [a, above core benzene plane; b, below]. The adduct crystallizes in the monoclinic space group P21/c with a=16.559(3), b=23.233(5), c=18.640(4), Å, β=114.49(3)° and Dc=1.363 gcm-3 for Z=4. The refinement is based on 4621 observed reflections and gives a final R value of 0.069.

本文言語English
ページ(範囲)27-32
ページ数6
ジャーナルSupramolecular Chemistry
10
1
出版ステータスPublished - 1998
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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