Deep-blue light emission with a wide-bandgap naphthalene-derivative liquid organic semiconductor host

Naofumi Kobayashi, Hiroyuki Kuwae, Juro Oshima, Ryoichi Ishimatsu, Shuya Tashiro, Toshihiko Imato, Chihaya Adachi, Shuichi Shoji, Jun Mizuno

研究成果: Conference contribution

抄録

We developed a novel naphthalene-derivative to function as a wide-bandgap liquid organic semiconductor (LOS) host material for the limited range of liquid deep-blue light-emitting materials that have been developed to date. The naphthalene-derivative, 1-naphthaleneacetic acid 2-ethylhexyl ester (NLQ) was synthesized as a LOS, by introducing an ethylhexyl group into naphthalene. 9,10-Diphenyl anthracene (DPA) was doped into NLQ as a guest deep-blue dye. From the absorption spectrum, the bandgap energy of NLQ was estimated to be 4.13 eV, indicating that NLQ has the widest bandgap energy of any such host material so far as we know. Deep-blue electroluminescence (EL) emission in a liquid state was obtained by doping DPA into NLQ. Light emission could be achieved by a combination of Förster resonance energy transfer and direct recombination of trapped holes and electrons because the bandgap energy of DPA is straddle by that of the wide-bandgap NLQ. Thus, NLQ is shown to be a promising wide-bandgap LOS host material, which allows deep-blue light emission and may have applications in liquid organic light-emitting diodes.

元の言語English
ホスト出版物のタイトルOrganic Photonic Materials and Devices XIX 2017
出版者SPIE
10101
ISBN(電子版)9781510606432
DOI
出版物ステータスPublished - 2017
イベントOrganic Photonic Materials and Devices XIX 2017 - San Francisco, United States
継続期間: 2017 1 302017 2 1

Other

OtherOrganic Photonic Materials and Devices XIX 2017
United States
San Francisco
期間17/1/3017/2/1

Fingerprint

Organic Semiconductors
Blue Light
Semiconducting organic compounds
Light emission
organic semiconductors
Naphthalene
naphthalene
light emission
Energy gap
Liquid
Derivatives
Derivative
Anthracene
Liquids
liquids
anthracene
Energy
Electroluminescence
Organic Light-emitting Diodes
organic liquids

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

これを引用

Kobayashi, N., Kuwae, H., Oshima, J., Ishimatsu, R., Tashiro, S., Imato, T., ... Mizuno, J. (2017). Deep-blue light emission with a wide-bandgap naphthalene-derivative liquid organic semiconductor host. : Organic Photonic Materials and Devices XIX 2017 (巻 10101). [101011B] SPIE. https://doi.org/10.1117/12.2251640

Deep-blue light emission with a wide-bandgap naphthalene-derivative liquid organic semiconductor host. / Kobayashi, Naofumi; Kuwae, Hiroyuki; Oshima, Juro; Ishimatsu, Ryoichi; Tashiro, Shuya; Imato, Toshihiko; Adachi, Chihaya; Shoji, Shuichi; Mizuno, Jun.

Organic Photonic Materials and Devices XIX 2017. 巻 10101 SPIE, 2017. 101011B.

研究成果: Conference contribution

Kobayashi, N, Kuwae, H, Oshima, J, Ishimatsu, R, Tashiro, S, Imato, T, Adachi, C, Shoji, S & Mizuno, J 2017, Deep-blue light emission with a wide-bandgap naphthalene-derivative liquid organic semiconductor host. : Organic Photonic Materials and Devices XIX 2017. 巻. 10101, 101011B, SPIE, Organic Photonic Materials and Devices XIX 2017, San Francisco, United States, 17/1/30. https://doi.org/10.1117/12.2251640
Kobayashi N, Kuwae H, Oshima J, Ishimatsu R, Tashiro S, Imato T その他. Deep-blue light emission with a wide-bandgap naphthalene-derivative liquid organic semiconductor host. : Organic Photonic Materials and Devices XIX 2017. 巻 10101. SPIE. 2017. 101011B https://doi.org/10.1117/12.2251640
Kobayashi, Naofumi ; Kuwae, Hiroyuki ; Oshima, Juro ; Ishimatsu, Ryoichi ; Tashiro, Shuya ; Imato, Toshihiko ; Adachi, Chihaya ; Shoji, Shuichi ; Mizuno, Jun. / Deep-blue light emission with a wide-bandgap naphthalene-derivative liquid organic semiconductor host. Organic Photonic Materials and Devices XIX 2017. 巻 10101 SPIE, 2017.
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AU - Kobayashi, Naofumi

AU - Kuwae, Hiroyuki

AU - Oshima, Juro

AU - Ishimatsu, Ryoichi

AU - Tashiro, Shuya

AU - Imato, Toshihiko

AU - Adachi, Chihaya

AU - Shoji, Shuichi

AU - Mizuno, Jun

PY - 2017

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N2 - We developed a novel naphthalene-derivative to function as a wide-bandgap liquid organic semiconductor (LOS) host material for the limited range of liquid deep-blue light-emitting materials that have been developed to date. The naphthalene-derivative, 1-naphthaleneacetic acid 2-ethylhexyl ester (NLQ) was synthesized as a LOS, by introducing an ethylhexyl group into naphthalene. 9,10-Diphenyl anthracene (DPA) was doped into NLQ as a guest deep-blue dye. From the absorption spectrum, the bandgap energy of NLQ was estimated to be 4.13 eV, indicating that NLQ has the widest bandgap energy of any such host material so far as we know. Deep-blue electroluminescence (EL) emission in a liquid state was obtained by doping DPA into NLQ. Light emission could be achieved by a combination of Förster resonance energy transfer and direct recombination of trapped holes and electrons because the bandgap energy of DPA is straddle by that of the wide-bandgap NLQ. Thus, NLQ is shown to be a promising wide-bandgap LOS host material, which allows deep-blue light emission and may have applications in liquid organic light-emitting diodes.

AB - We developed a novel naphthalene-derivative to function as a wide-bandgap liquid organic semiconductor (LOS) host material for the limited range of liquid deep-blue light-emitting materials that have been developed to date. The naphthalene-derivative, 1-naphthaleneacetic acid 2-ethylhexyl ester (NLQ) was synthesized as a LOS, by introducing an ethylhexyl group into naphthalene. 9,10-Diphenyl anthracene (DPA) was doped into NLQ as a guest deep-blue dye. From the absorption spectrum, the bandgap energy of NLQ was estimated to be 4.13 eV, indicating that NLQ has the widest bandgap energy of any such host material so far as we know. Deep-blue electroluminescence (EL) emission in a liquid state was obtained by doping DPA into NLQ. Light emission could be achieved by a combination of Förster resonance energy transfer and direct recombination of trapped holes and electrons because the bandgap energy of DPA is straddle by that of the wide-bandgap NLQ. Thus, NLQ is shown to be a promising wide-bandgap LOS host material, which allows deep-blue light emission and may have applications in liquid organic light-emitting diodes.

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KW - Naphthalene-derivative

KW - Wide-bandgap material

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