Deformation of boron networks at the LaB6(111) surface

E. Rokuta, N. Yamamoto, Y. Hasegawa, M. Trenary, T. Nagao, C. Oshima, S. Otani

研究成果: Article

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The dispersion of the phonons of the LaB6(111) surface has been measured and reproduced on the basis of lattice dynamical calculations. The surface force constants were found to be different from the bulk force constants. In particular, the force constant of an interoctahedral boron-boron bond at the surface increases by 50% from the corresponding bulk force constant. From the relationship between the force constant and bond length in various hexaborides, we have estimated the contraction of the interoctahedral bond length to be 0.007 nm. The deformation of the boron network on the (111) surface, the behavior of which is similar to that on the (100) surface, is explained by the inherent nature of the boron network.

元の言語English
ページ(範囲)363-370
ページ数8
ジャーナルSurface Science
416
発行部数3
出版物ステータスPublished - 1998 10 30

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Condensed Matter Physics
  • Surfaces and Interfaces

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    Rokuta, E., Yamamoto, N., Hasegawa, Y., Trenary, M., Nagao, T., Oshima, C., & Otani, S. (1998). Deformation of boron networks at the LaB6(111) surface. Surface Science, 416(3), 363-370.