Degree of branching of highly branched polyurethanes synthesized via the Oligomeric A2 Plus B3 methodology

Ann R. Fornof, Thomas E. Glass, Timothy Edward Long*

*この研究の対応する著者

研究成果: Article査読

43 被引用数 (Scopus)

抄録

The oligomeric A2 plus monomeric B3 synthetic methodology provided highly branched, poly(ether urethane)s based on IMP (B 3) and isocyanate endcapped polyethers. 13C NMR spectroscopic assignments for the branched polyurethanes were verified using model urethane-containing compounds based on TMP and a monofunctional isocyanate (either cyclohexyl or phenyl isocyanate (PI)). Derivatization of hydroxyl endgroups with trifluoroacetic anhydride enhanced the 13C NMR resolution in spectra for branched polyurethanes. The 13C NMR resonance for the linear unit exhibited a broad shoulder due to quaternary carbons that were attributed to cyclic species in the highly branched polyurethanes. The classical DB calculation revealed the efficiency of the 83 monomer for branching; however, an equation that incorporated the linear contribution of the A2 oligomer provided a more accurate DB for highly branched polyurethanes.

本文言語English
ページ(範囲)1197-1206
ページ数10
ジャーナルMacromolecular Chemistry and Physics
207
14
DOI
出版ステータスPublished - 2006 7 24
外部発表はい

ASJC Scopus subject areas

  • 凝縮系物理学
  • 物理化学および理論化学
  • ポリマーおよびプラスチック
  • 有機化学
  • 材料化学

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