抄録
Grafting of polymer brushes if of high interest towards intelligent materials systems with stimuli response. While there has been a lot of interest on chemically modified attachment of initiators towards surfaces for surface initiated polymerization (SIP), very little work has been done on modifying electrode surfaces via electrochemical methods. To address this issue, we have proposed to use a preformed RAFT agent with an electrochemically active moiety to mediate SI-RAFT polymerization as well as grafting of CTA's on electrode surfaces to promote RAFT-SIP. In particular, we have used the first generation CTA (G1-CTA), which had been reported to facilitate RAFT polymerization in solution. The presence of the electro-active carbazole group in this RAFT agent enables its immobilization on the electrode surface through electro-grafting.
| 元の言語 | English |
|---|---|
| ホスト出版物のタイトル | Smart Coatings III |
| 出版者 | American Chemical Society |
| ページ | 63-72 |
| ページ数 | 10 |
| 巻 | 1050 |
| ISBN（印刷物） | 9780841225657 |
| DOI | |
| 出版物ステータス | Published - 2010 11 10 |
| 外部発表 | Yes |
出版物シリーズ
| 名前 | ACS Symposium Series |
|---|---|
| 巻 | 1050 |
| ISSN（印刷物） | 0097-6156 |
| ISSN（電子版） | 1947-5918 |
Fingerprint
ASJC Scopus subject areas
- Chemistry(all)
- Chemical Engineering(all)
これを引用
Design and synthesis of living-free Electroactive Dendron end-functionalized macromolecules : Surface grafting studies. / Advincula, Rigoberto C.; Tria, Maria Celeste.
Smart Coatings III. 巻 1050 American Chemical Society, 2010. p. 63-72 (ACS Symposium Series; 巻 1050).研究成果: Conference contribution
}
TY - GEN
T1 - Design and synthesis of living-free Electroactive Dendron end-functionalized macromolecules
T2 - Surface grafting studies
AU - Advincula, Rigoberto C.
AU - Tria, Maria Celeste
PY - 2010/11/10
Y1 - 2010/11/10
N2 - Grafting of polymer brushes if of high interest towards intelligent materials systems with stimuli response. While there has been a lot of interest on chemically modified attachment of initiators towards surfaces for surface initiated polymerization (SIP), very little work has been done on modifying electrode surfaces via electrochemical methods. To address this issue, we have proposed to use a preformed RAFT agent with an electrochemically active moiety to mediate SI-RAFT polymerization as well as grafting of CTA's on electrode surfaces to promote RAFT-SIP. In particular, we have used the first generation CTA (G1-CTA), which had been reported to facilitate RAFT polymerization in solution. The presence of the electro-active carbazole group in this RAFT agent enables its immobilization on the electrode surface through electro-grafting.
AB - Grafting of polymer brushes if of high interest towards intelligent materials systems with stimuli response. While there has been a lot of interest on chemically modified attachment of initiators towards surfaces for surface initiated polymerization (SIP), very little work has been done on modifying electrode surfaces via electrochemical methods. To address this issue, we have proposed to use a preformed RAFT agent with an electrochemically active moiety to mediate SI-RAFT polymerization as well as grafting of CTA's on electrode surfaces to promote RAFT-SIP. In particular, we have used the first generation CTA (G1-CTA), which had been reported to facilitate RAFT polymerization in solution. The presence of the electro-active carbazole group in this RAFT agent enables its immobilization on the electrode surface through electro-grafting.
UR - http://www.scopus.com/inward/record.url?scp=84905588134&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84905588134&partnerID=8YFLogxK
U2 - 10.1021/bk-2010-1050.ch005
DO - 10.1021/bk-2010-1050.ch005
M3 - Conference contribution
AN - SCOPUS:84905588134
SN - 9780841225657
VL - 1050
T3 - ACS Symposium Series
SP - 63
EP - 72
BT - Smart Coatings III
PB - American Chemical Society
ER -