Design and synthesis of living-free Electroactive Dendron end-functionalized macromolecules: Surface grafting studies

Rigoberto C. Advincula, Maria Celeste Tria

研究成果: Conference contribution

1 引用 (Scopus)

抄録

Grafting of polymer brushes if of high interest towards intelligent materials systems with stimuli response. While there has been a lot of interest on chemically modified attachment of initiators towards surfaces for surface initiated polymerization (SIP), very little work has been done on modifying electrode surfaces via electrochemical methods. To address this issue, we have proposed to use a preformed RAFT agent with an electrochemically active moiety to mediate SI-RAFT polymerization as well as grafting of CTA's on electrode surfaces to promote RAFT-SIP. In particular, we have used the first generation CTA (G1-CTA), which had been reported to facilitate RAFT polymerization in solution. The presence of the electro-active carbazole group in this RAFT agent enables its immobilization on the electrode surface through electro-grafting.

元の言語English
ホスト出版物のタイトルSmart Coatings III
出版者American Chemical Society
ページ63-72
ページ数10
1050
ISBN(印刷物)9780841225657
DOI
出版物ステータスPublished - 2010 11 10
外部発表Yes

出版物シリーズ

名前ACS Symposium Series
1050
ISSN(印刷物)0097-6156
ISSN(電子版)1947-5918

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Macromolecules
Polymerization
Electrodes
Intelligent materials
Brushes
dendron
Polymers

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

これを引用

Advincula, R. C., & Tria, M. C. (2010). Design and synthesis of living-free Electroactive Dendron end-functionalized macromolecules: Surface grafting studies. : Smart Coatings III (巻 1050, pp. 63-72). (ACS Symposium Series; 巻数 1050). American Chemical Society. https://doi.org/10.1021/bk-2010-1050.ch005

Design and synthesis of living-free Electroactive Dendron end-functionalized macromolecules : Surface grafting studies. / Advincula, Rigoberto C.; Tria, Maria Celeste.

Smart Coatings III. 巻 1050 American Chemical Society, 2010. p. 63-72 (ACS Symposium Series; 巻 1050).

研究成果: Conference contribution

Advincula, RC & Tria, MC 2010, Design and synthesis of living-free Electroactive Dendron end-functionalized macromolecules: Surface grafting studies. : Smart Coatings III. 巻. 1050, ACS Symposium Series, 巻. 1050, American Chemical Society, pp. 63-72. https://doi.org/10.1021/bk-2010-1050.ch005
Advincula RC, Tria MC. Design and synthesis of living-free Electroactive Dendron end-functionalized macromolecules: Surface grafting studies. : Smart Coatings III. 巻 1050. American Chemical Society. 2010. p. 63-72. (ACS Symposium Series). https://doi.org/10.1021/bk-2010-1050.ch005
Advincula, Rigoberto C. ; Tria, Maria Celeste. / Design and synthesis of living-free Electroactive Dendron end-functionalized macromolecules : Surface grafting studies. Smart Coatings III. 巻 1050 American Chemical Society, 2010. pp. 63-72 (ACS Symposium Series).
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