Design and synthesis of living-free Electroactive Dendron end-functionalized macromolecules: Surface grafting studies

Rigoberto C. Advincula, Maria Celeste Tria

研究成果: Conference contribution

1 被引用数 (Scopus)

抄録

Grafting of polymer brushes if of high interest towards intelligent materials systems with stimuli response. While there has been a lot of interest on chemically modified attachment of initiators towards surfaces for surface initiated polymerization (SIP), very little work has been done on modifying electrode surfaces via electrochemical methods. To address this issue, we have proposed to use a preformed RAFT agent with an electrochemically active moiety to mediate SI-RAFT polymerization as well as grafting of CTA's on electrode surfaces to promote RAFT-SIP. In particular, we have used the first generation CTA (G1-CTA), which had been reported to facilitate RAFT polymerization in solution. The presence of the electro-active carbazole group in this RAFT agent enables its immobilization on the electrode surface through electro-grafting.

本文言語English
ホスト出版物のタイトルSmart Coatings III
出版社American Chemical Society
ページ63-72
ページ数10
1050
ISBN(印刷版)9780841225657
DOI
出版ステータスPublished - 2010 11月 10
外部発表はい

出版物シリーズ

名前ACS Symposium Series
1050
ISSN(印刷版)0097-6156
ISSN(電子版)1947-5918

ASJC Scopus subject areas

  • 化学 (全般)
  • 化学工学(全般)

フィンガープリント

「Design and synthesis of living-free Electroactive Dendron end-functionalized macromolecules: Surface grafting studies」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル