Design, synthesis, and photochemical behavior of poly(benzyl ester) dendrimers with azobenzene groups throughout their architecture

Shuangxi Wang*, Ximeng Wang, Lijuan Li, Rigoberto C. Advincula

*この研究の対応する著者

研究成果: Article査読

71 被引用数 (Scopus)

抄録

A new class of dendrons and dendrimers containing azobenzene units (bearing up to 29 azobenzene groups for four generations) were designed and synthesized with the convergent method, which uses azobenzene derivatives as monomers and benzyl ester groups as linkages leading to photoresponsive dendrons and dendrimers with azobenzene units throughout their architecture. Photochemical isomerization experiments revealed that all of the dendrons and dendrimers undergo trans-cis isomerization by irradiation and cis-trans isomerization by either irradiation or heating.

本文言語English
ページ(範囲)9073-9084
ページ数12
ジャーナルJournal of Organic Chemistry
69
26
DOI
出版ステータスPublished - 2004 12月 24
外部発表はい

ASJC Scopus subject areas

  • 有機化学

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