Development of pH-sensitive spin-crossover iron(II) complex films, [FeII(diAMsar)] Nafion: Manipulation of the spin state by proton concentration

Hajime Kamebuchi*, Taketomo Jo, Hideharu Shimizu, Atsushi Okazawa, Masaya Enomoto, Norimichi Kojima

*この研究の対応する著者

研究成果: Article査読

15 被引用数 (Scopus)

抄録

We newly synthesized transparent films composed of pHsensitive spin-crossover complex [FeII(diAMsar)] (diAMsar: 1,8-diaminosarcophagine) and an ion-exchange polymer, Nafion, having different colors corresponding to proton concentration. The UVvis spectroscopic measurements revealed that the films, which were provided under pH 4, 7, and 10 conditions, showed the spin state depending on pH.

本文言語English
ページ(範囲)888-889
ページ数2
ジャーナルChemistry Letters
40
8
DOI
出版ステータスPublished - 2011
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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