Development of pressure sensitive molecular film suitable to pressure measurement of high Knudsen number flows

yu Matsuda, Hideo Mori, Tomohide Niimi, Hiroyuki Uenishi, Madoka Hirako

研究成果: Article

1 引用 (Scopus)

抄録

The pressure-sensitive paint (PSP) has potential as a diagnostic tool for pressure measurement in the high Knudsen number regime because it works as a so-called "molecular sensor". However, there are few reports concerning application of the PSP to micro devices because the conventional PSP is too thick owing to the use of polymer binder. In this study, we have adopted Langmuir-Blodgett (LB) technique to fabricate pressure sensitive molecular films (PSMFs) using Pd(II) Octaethylporphine (PdOEP) and Pd(II) Mesoporphyrin IX (PdMP), and have tested these PSMFs to evaluate the feasibility of the pressure measurement around micro-devices. It is clarified that the PSMF composed of PdMP has higher sensitivity than that of PdOEP. Since it is also considered that the sensitivity of PSMFs can be increased by introducing arachidic acid as the spacer molecules to prevent the aggregation of luminescent molecules, we have produced PSMFs with several molar ratio of PdMP to arachidic acid. At the most suitable ratio, the PSMF has sufficient sensitivity in the low pressure region with high Knudsen number, even if the amount of the luminescent molecules in the PSMF layer is smaller than those in conventional PSPs. This indicates that the PSMF is feasible to measure the pressure in high Knudsen number flows such as micro-flows.

元の言語English
ページ(範囲)1475-1482
ページ数8
ジャーナルNihon Kikai Gakkai Ronbunshu, B Hen/Transactions of the Japan Society of Mechanical Engineers, Part B
72
発行部数6
出版物ステータスPublished - 2006 6 1
外部発表Yes

Fingerprint

Knudsen flow
pressure measurement
Pressure measurement
pressure sensitive paints
Paint
sensitivity
molecules
Molecules
acids
spacers
Acids
low pressure
Binders
sensors
polymers
Agglomeration

ASJC Scopus subject areas

  • Mechanical Engineering

これを引用

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abstract = "The pressure-sensitive paint (PSP) has potential as a diagnostic tool for pressure measurement in the high Knudsen number regime because it works as a so-called {"}molecular sensor{"}. However, there are few reports concerning application of the PSP to micro devices because the conventional PSP is too thick owing to the use of polymer binder. In this study, we have adopted Langmuir-Blodgett (LB) technique to fabricate pressure sensitive molecular films (PSMFs) using Pd(II) Octaethylporphine (PdOEP) and Pd(II) Mesoporphyrin IX (PdMP), and have tested these PSMFs to evaluate the feasibility of the pressure measurement around micro-devices. It is clarified that the PSMF composed of PdMP has higher sensitivity than that of PdOEP. Since it is also considered that the sensitivity of PSMFs can be increased by introducing arachidic acid as the spacer molecules to prevent the aggregation of luminescent molecules, we have produced PSMFs with several molar ratio of PdMP to arachidic acid. At the most suitable ratio, the PSMF has sufficient sensitivity in the low pressure region with high Knudsen number, even if the amount of the luminescent molecules in the PSMF layer is smaller than those in conventional PSPs. This indicates that the PSMF is feasible to measure the pressure in high Knudsen number flows such as micro-flows.",
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T1 - Development of pressure sensitive molecular film suitable to pressure measurement of high Knudsen number flows

AU - Matsuda, yu

AU - Mori, Hideo

AU - Niimi, Tomohide

AU - Uenishi, Hiroyuki

AU - Hirako, Madoka

PY - 2006/6/1

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KW - High Knudsen Number Flow

KW - LB Film

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