Directed C-H alkenylation of quinoline N-oxides at the C-8 position using a cationic rhodium(I) catalyst

Takanori Shibata, Yusuke Matsuo

研究成果: Article

52 被引用数 (Scopus)

抄録

The cationic rhodium-catalyzed alkenylation proceeds at the C-8 position of quinoline N-oxides. Regioselective C-H bond activation was achieved by the directing effect of the anionic oxygen of an N-oxide moiety, which can be readily removed by reductive treatment. A variety of 8-alkenylated quinoline N-oxides was obtained in moderate to high yields.

元の言語English
ページ(範囲)1516-1520
ページ数5
ジャーナルAdvanced Synthesis and Catalysis
356
発行部数7
DOI
出版物ステータスPublished - 2014 5 5

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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