Dynamic hemicarcerands and hemicarceplexes

Stephen Ro, Stuart J. Rowan, Anthony R. Pease, Donald J. Cram, J. Fraser Stoddart

研究成果: Article査読

89 被引用数 (Scopus)

抄録

(equation presented) The reversible nature of the imine bond formation in CDCl3 solution has been exploited to exchange substituted for unsubstituted m-phenylenediamine (MPD) units in hemicarcerand octaimines. Moreover, acid-catalyzed imine exchange has been shown to provide a novel mechanism whereby ferrocene (Fc) can be released as an entrapped guest from the hemicarceplex C2B4⊙Fc dissolved in CDCl3 to give the hemicarcerand C2B4 when excess of both MPD and trifluoroacetic acid are present.

本文言語English
ページ(範囲)2411-2414
ページ数4
ジャーナルOrganic Letters
2
16
出版ステータスPublished - 2000 8 10
外部発表はい

ASJC Scopus subject areas

  • Molecular Medicine

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