Effect of Glass Transition on Electrical Conduction Characteristics of Poly-L-lactic Acid

Yasumasa Maeno, Yuya Yamaguchi, Naoshi Hirai, Yoshimichi Ohki, Toshikatsu Tanaka, Yoshiro Tajitsu, Masanori Kohtoh, Shigemitsu Okabe

研究成果: Article査読

23 被引用数 (Scopus)

抄録

The temperature dependence of electrical conduction current in additive-free poly-L-lactic acid was measured from 20°C to 90°C under application of dc 2.5 kV. Although the current obeys the Arrhenius formula, a hump appears in some conditions, depending on whether the temperature is being ascended or descended, and also on whether the sample was poled or short-circuited prior to the measurements. Even under short-circuit condition, a similar hump alone appears if the sample was poled by a dc voltage beforehand. From these results, it is assumed that orientational polarization or depolarization occurs around 74°C by the glass transition, and that its resultant current and the conduction current overlap with each other. The fact that polar groups, mainly carbonyl groups, in the sample really changed their directions was confirmed by Fourier-transform infrared spectroscopy. The permittivity also increases around 74°C. These facts indicate that the number of dipoles, which become possible to rotate toward the direction of electric field, is increased by the glass transition.

本文言語English
ページ(範囲)254-260
ページ数7
ジャーナルIEEJ Transactions on Fundamentals and Materials
125
3
DOI
出版ステータスPublished - 2005

ASJC Scopus subject areas

  • 電子工学および電気工学

フィンガープリント

「Effect of Glass Transition on Electrical Conduction Characteristics of Poly-L-lactic Acid」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル