EFFECT OF UNDERPOTENTIAL DEPOSITION ON THE KINETICS OF THE CHROMOUS-CHROMIC COUPLE.

C. D. Wu, E. J. Calvo, Daniel Alberto Scherson, M. Reid, E. Yeager

研究成果: Paper査読

抄録

The aim of this work has been to investigate the effect of the modification of Ag surface by simultaneous underpotential deposition (upd) of Pb and Tl on the electroreduction of Cr(OH//2)Cl**2** plus . The upd layers of Pb and Tl inhibit the electroreduction of Cr(OH//2)//5Cl**2** plus and the effect is a linear function of the upd metal coverage. The most likely explanation is that the interaction of the halide as a bridging species with the upd covered surface is less favorable than that with the substrate alone.

本文言語English
ページ412-414
ページ数3
出版ステータスPublished - 1984 12 1
外部発表はい

ASJC Scopus subject areas

  • Engineering(all)

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