Electrical conduction and breakdown properties of several biodegradable polymers

Y. Ohki*, N. Hirai

*この研究の対応する著者

研究成果: Article査読

42 被引用数 (Scopus)

抄録

In order to respond to soaring public concern about environmental protection, various biodegradable polymers have been developed. The present paper reports the electrical conduction and breakdown properties of various biodegradable polymers such as poly-L-lactic acid (PLLA), polyethylene terephthalate succinate (PETS), polycaprolactone butylene succinate (PCL-BS), polybutylene succinate (PBS), polybutylene succinate adipate (PBSA), and polyhydroxybutyrate/valerate (PHB/V) in comparison to those of low-density polyethylene (LDPE). While the permittivity and conductivity of PLLA and PETS are comparable to LDPE, those of PCL-BS and PBS are much higher. The conductivity is also higher in PBSA. This is because PLLA and PETS are in the glass state at room temperature, while PCL-BS, PBS, and PBSA are in the rubber state. Furthermore, PLLA and PETS show a strong temperature dependence of the conductivity, which is divided into two or three regions, and they also show thermally stimulated polarization or depolarization current around their respective glass transition temperatures. In contrast to the large difference in conductivity among different kinds of samples, all the polymers tested have almost similar impulse breakdown strength at room temperature. As for dc or ac breakdown strength, PLLA and PETS show a relatively higher strength than PCL-BS and PBS.

本文言語English
ページ(範囲)1559-1566
ページ数8
ジャーナルIEEE Transactions on Dielectrics and Electrical Insulation
14
6
DOI
出版ステータスPublished - 2007 12月

ASJC Scopus subject areas

  • 電子工学および電気工学

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