Electro-copolymerization of layer-by-layer deposited polythiophene and polycarbazole precursor ultrathin films

Paralee Waenkaew, Prasad Taranekar, Sukon Phanichphant, Rigoberto C. Advincula

研究成果: Article

26 引用 (Scopus)

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The synthesis, layer-by-layer deposition, and electro-copolymerization of precursor polyelectrolyte multilayer ultrathin films with thiophene and carbazole electroactive groups are described. The interest is in observing an electrochemical cross-linking approach towards a highly ordered ultrathin film that contains two types of monomers to result in possible layer-limited homo-and copolymerization. A uniform linear growth with alternate deposition of the polyelectrolytes is observed. The multilayer films were then electrochemically polymerized anodically by cyclic voltammetry (CV), which results in copolymerization between two different electroactive groups. Cross-linking of the layers was verified by CV and spectroelectrochemistry data with very good linear electro-copolymerizability.

元の言語English
ページ(範囲)1522-1527
ページ数6
ジャーナルMacromolecular Rapid Communications
28
発行部数15
DOI
出版物ステータスPublished - 2007 8 1
外部発表Yes

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

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