Electro-oxidative Polymerization of 2, 6-DimethyIphenoxide Ion in the Presence of Bromide Ion as a Mediator

Kimihisa Yamamoto, Hiroyuki Nishide, Eishun Tsuchida

研究成果: Article査読

1 被引用数 (Scopus)

抄録

Anodic oxidation of 2, 6-dimethylphenol in an alkaline dichloromethane in the presence of bromide ion gave poly[oxy(2, 6-dimethyl-1, 4-phenylene] with high efficiency. 4-Bromo-2, 6-dimethylphenol was isolated from the reaction mixture during the electrolysis. Bromide ion is assumed to serve as a mediator of electro-oxidative polymerization. The mechanism of this polymerization was discussed on the basis of results obtained in the measurements including cyclic voltammetry and double potential-step chronocoulometry.

本文言語English
ページ(範囲)152-156
ページ数5
ジャーナルNippon Kagaku Kaishi
1986
2
DOI
出版ステータスPublished - 1986

ASJC Scopus subject areas

  • Chemistry(all)

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