Electro-oxidative polymerization of p-dialkoxybenzenes and its mechanism

K. Yamamoto, T. Asada, Hiroyuki Nishide, E. Tsuchida

研究成果: Article査読

11 被引用数 (Scopus)

抄録

p-Dimethoxybenzene is anodically oxidative polymerized to poly(2,5-dimethoxy-1,4-phenylene). p-Diethoxybenzene and p-dipropoxybenzene are also polymerized because the alkoxy groups reduce oxidation peak potentials of the benzene derivatives. This electro-oxidative polymerization is studied with the preparative electrolysis and cyclic voltammetry. The polymerization contains an electrophilic reaction of cation radical of the benzene and proceeds through a stepwise or chain propagation according to the supplied potential.

本文言語English
ページ(範囲)533-538
ページ数6
ジャーナルPolymer Bulletin
19
6
DOI
出版ステータスPublished - 1988 6

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

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