Electron spin resonance in Langmuir-Blodgett films of a merocyanine dye and its isotope-substituted analogs

Shin ichi Kuroda*, Keiichi Ikegami, Yuka Tabe, Kazuhiro Saito, Mitsuyoshi Saito, Michio Sugi, Shigeo Yasui

*この研究の対応する著者

研究成果: Article査読

10 被引用数 (Scopus)

抄録

Stable radical species existing in mixed Langmuir-Blodgett films of a merocyanine dye and arachidic acid are studied through their hyperfine couplings using the isotope substitution technique. One of the species shows a nitrogen hyperfine structure possibly arising from one of the two nitrogen sites in the molecule. With the employment of two dye analogs in which either one of the 14N nuclei is replaced by 15N, the observed nitrogen site has been identified to be the one in benzothiazole. That is, the wave function of the radical is directly associated with the dye chromophore. The photo-induced spectra have shown a similar change as the dark spectra upon 15N-substitution, indicating that the dark and photo-induced signals arise from a common species. These facts together with the recently observed correlation between the anisotropic behaviour of ESR and optical J-band strongly suggest an intermolecular charge transfer in J-aggregates as the origin of radical generation.

本文言語English
ページ(範囲)512-514
ページ数3
ジャーナルThin Solid Films
210-211
PART 2
DOI
出版ステータスPublished - 1992 4月 30
外部発表はい

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 表面および界面
  • 表面、皮膜および薄膜
  • 金属および合金
  • 材料化学

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