Interfacial electron-transfer reactions between polymer-bonded metal complexes and the substrates in solution phase were studied to show colloid aspects of polymer catalysis. A polymer-bonded metal complex often shows a specifically catalytic behavior, because the electron-transfer reactivity is strongly affected by the polymer matrix that surrounds the complex. A polymer-Cu complex coated electrode was successfully applied as the interfacial catalyst for the oxidative polymerization of phenol.
|ホスト出版物のタイトル||ACS Symposium Series|
|編集者||E.J. Vandenberg, A. Blumstein, M.J. Bowden, Jett C. Arthur, Joginder Lal, R.M. Ottenbrite|
|Place of Publication||Washington, DC, USA|
|出版ステータス||Published - 1983|
ASJC Scopus subject areas