Electro‐oxidative polymerization of 1,3‐Cyclohexadiene

Kimihisa Yamamoto; Toshio Asada; Hiroyuki Nishide; Eishun Tsuchida

doi:10.1002/pat.1990.220010303

Electro‐oxidative polymerization of 1,3‐Cyclohexadiene

Kimihisa Yamamoto, Toshio Asada, Hiroyuki Nishide, Eishun Tsuchida^*

^*この研究の対応する著者

理工学術院総合研究所

研究成果: Article › 査読

2 被引用数 (Scopus)

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1,3‐Cyclohexadiene is electropolymerized at a lower applied potential, compared with the polymerization of other alkene compounds, to give insoluble polymer film on an electrode. The formed polymer contains a phenylene repeated unit, which is confirmed by IR, ¹H‐ and ¹³C‐NMR spectroscopy. Poly(cyclohexene) produced by the electropolymerization is partially aromatized by the oxidation to form a phenylene unit which is accompanied by an elimination of a proton.

本文言語	English
ページ（範囲）	207-210
ページ数	4
ジャーナル	Polymers for Advanced Technologies
巻	1
号	3-4
DOI	https://doi.org/10.1002/pat.1990.220010303
出版ステータス	Published - 1990

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10.1002/pat.1990.220010303

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title = "Electro‐oxidative polymerization of 1,3‐Cyclohexadiene",

abstract = "1,3‐Cyclohexadiene is electropolymerized at a lower applied potential, compared with the polymerization of other alkene compounds, to give insoluble polymer film on an electrode. The formed polymer contains a phenylene repeated unit, which is confirmed by IR, 1H‐ and 13C‐NMR spectroscopy. Poly(cyclohexene) produced by the electropolymerization is partially aromatized by the oxidation to form a phenylene unit which is accompanied by an elimination of a proton.",

keywords = "Cationic oxidation, Cyclohexadiene, Electro‐polymerization, Poly(cyclohexene), Poly(phenylene)",

author = "Kimihisa Yamamoto and Toshio Asada and Hiroyuki Nishide and Eishun Tsuchida",

year = "1990",

doi = "10.1002/pat.1990.220010303",

language = "English",

volume = "1",

pages = "207--210",

journal = "Polymers for Advanced Technologies",

issn = "1042-7147",

publisher = "John Wiley and Sons Ltd",

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TY - JOUR

T1 - Electro‐oxidative polymerization of 1,3‐Cyclohexadiene

AU - Yamamoto, Kimihisa

AU - Asada, Toshio

AU - Nishide, Hiroyuki

AU - Tsuchida, Eishun

PY - 1990

Y1 - 1990

N2 - 1,3‐Cyclohexadiene is electropolymerized at a lower applied potential, compared with the polymerization of other alkene compounds, to give insoluble polymer film on an electrode. The formed polymer contains a phenylene repeated unit, which is confirmed by IR, 1H‐ and 13C‐NMR spectroscopy. Poly(cyclohexene) produced by the electropolymerization is partially aromatized by the oxidation to form a phenylene unit which is accompanied by an elimination of a proton.

AB - 1,3‐Cyclohexadiene is electropolymerized at a lower applied potential, compared with the polymerization of other alkene compounds, to give insoluble polymer film on an electrode. The formed polymer contains a phenylene repeated unit, which is confirmed by IR, 1H‐ and 13C‐NMR spectroscopy. Poly(cyclohexene) produced by the electropolymerization is partially aromatized by the oxidation to form a phenylene unit which is accompanied by an elimination of a proton.

KW - Cationic oxidation

KW - Cyclohexadiene

KW - Electro‐polymerization

KW - Poly(cyclohexene)

KW - Poly(phenylene)

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U2 - 10.1002/pat.1990.220010303

DO - 10.1002/pat.1990.220010303

M3 - Article

AN - SCOPUS:84994986430

VL - 1

SP - 207

EP - 210

JO - Polymers for Advanced Technologies

JF - Polymers for Advanced Technologies

SN - 1042-7147

IS - 3-4

ER -

Electro‐oxidative polymerization of 1,3‐Cyclohexadiene

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