Electropolymerization of thiophene having porphyrin group and its application to superoxide sensor

Manabu Hoshino, Hidenori Murata, Kenichi Oyaizu, Makoto Yuasa

研究成果: Paper査読

抄録

Iron 5-(3-thienyl)-10,15,20-triethylporphyrin was electropolymerized in supercritical carbon dioxide (scCO2) to yield the corresponding conductive polymer film. The film was analyzed by scanning electron microscopy, laser microscopy and AFM. It was revealed that the thiophene-porphyrin film synthesized in scCO2 was more dense and smoother than those synthesized in dichloromethane. The electrocatalyst was applied to a superoxide anion radical sensor, and its detection sensitivity was drastically increased.

本文言語English
ページ数1
出版ステータスPublished - 2006 12 1
外部発表はい
イベント55th Society of Polymer Science Japan Symposium on Macromolecules - Toyama, Japan
継続期間: 2006 9 202006 9 22

Other

Other55th Society of Polymer Science Japan Symposium on Macromolecules
CountryJapan
CityToyama
Period06/9/2006/9/22

ASJC Scopus subject areas

  • Engineering(all)

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