Elucidation of the role of electric field on low temperature ammonia synthesis using isotopes

Kota Murakami, Ryo Manabe, Hideaki Nakatsubo, Tomohiro Yabe, Shuhei Ogo, Yasushi Sekine*

*この研究の対応する著者

研究成果: Article査読

21 被引用数 (Scopus)

抄録

We have found that an electric field brings high yield on low temperature catalytic ammonia synthesis over Cs/Ru/SrZrO3 catalyst. The role of the electric field is investigated based on kinetics and isotope effects.Results show that the electric field promotes proton hopping on the catalyst surface, and it brings a change in the reaction mechanism from the conventional one to the N2H+ intermediate mechanism. In the electric field, N2H+ intermediate plays an important role, enabling low-temperature ammonia synthesis.

本文言語English
ページ(範囲)271-275
ページ数5
ジャーナルCatalysis Today
303
DOI
出版ステータスPublished - 2018 4月 1

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

フィンガープリント

「Elucidation of the role of electric field on low temperature ammonia synthesis using isotopes」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル