Enantioselective addition of dialkylzincs to N-diphenylphosphinylimines using polymer-supported N,N-dialkylnorephedrines as chiral ligands

Takefumi Suzuki, Takanori Shibata, Kenso Soai

研究成果: Article査読

33 被引用数 (Scopus)

抄録

Chiral N,N-dialkylnorephedrines supported on polystyrene resin catalyse the enantioselective addition of dialkylzincs to N-diphenylphosphinylimine, affording optically active N-diphenylphosphinylamines with high enantiomeric excess. The influence on the enantioselectivity of the carbon-chain spacer between the chiral function and polymer resin has been examined. Reaction temperature- and solvent-dependency on the chiral polymer-catalysed reaction has also been examined.

本文言語English
ページ(範囲)2757-2760
ページ数4
ジャーナルJournal of the Chemical Society - Perkin Transactions 1
18
DOI
出版ステータスPublished - 1997 9 21
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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