Enantioselective divergent approaches to both (-)-platensimycin and (-)-platencin

Sho Hirai, Masahisa Nakada

研究成果: Article

49 被引用数 (Scopus)

抄録

Enantioselective divergent approaches to (-)-platencin and (-)-platensimycin have been developed. A rationally designed chiral synthetic intermediate, possessing a useful α,β-unsaturated sulfone functionality, which served as a masked ketone as well as a good Michael acceptor, was successfully prepared via the highly enantioselective catalytic asymmetric intramolecular cyclopropanation (CAIMCP) developed in our laboratory.

元の言語English
ページ(範囲)518-530
ページ数13
ジャーナルTetrahedron
67
発行部数2
DOI
出版物ステータスPublished - 2011 1 14

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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