Enantioselective incorporation of dicarboxylate guests by octacalcium phosphate

Taishi Yokoi, Shingo Machida, Yoshiyuki Sugahara, Masami Hashimoto, Satoshi Kitaoka

研究成果: Article

4 被引用数 (Scopus)

抄録

Enantioselectivity by octacalcium phosphate (OCP) is revealed through the incorporation of (S)-(-)-methylsuccinic acid (MeSuc) into its crystal lattice, with hardly any (R)-(+)-MeSuc incorporated. This phenomenon clearly indicates that OCP recognizes the steric structures of guest molecules, extending chiral recognition in inorganic materials to three-dimensional crystal growth.

本文言語English
ページ(範囲)6524-6527
ページ数4
ジャーナルChemical Communications
53
48
DOI
出版ステータスPublished - 2017 1 1

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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